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Article Dans Une Revue Journal of Porphyrins and Phthalocyanines Année : 2010

Bisporphyrin connected by pyrimidine: synthesis and photophysical properties

Résumé

We report the synthesis of a series of zinc porphyrins conjugated with pyrimidine derivatives. V shaped porphyrin dimer with a pyrimidine central core exhibits a planar geometry according to DFT computational studies, presents an internal charge transfer upon excitation proved by typical solvatochromic behavior and moderate two-photon absorption properties. Such porphyrin conjugates can afford valuable advantages in applications of TPA materials such as in photodynamic therapy and imaging of biological entities.

Domaines

Chimie organique
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Dates et versions

hal-00555074 , version 1 (12-01-2011)

Identifiants

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S. Achelle, N. Saettel, Patrice L. Baldeck, Marie-Paule Teulade-Fichou, Philippe Maillard. Bisporphyrin connected by pyrimidine: synthesis and photophysical properties. Journal of Porphyrins and Phthalocyanines, 2010, 14, pp.877-884. ⟨10.1142/S1088424610002720⟩. ⟨hal-00555074⟩
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