Impact of West African Monsoon convective transport and lightning NO_x production upon the upper tropospheric composition: a multi-model study

Brice Barret (1) , J. E. Williams (2) , Idir Bouarar (3) , X. Yang (4) , B. Josse (5) , Kathy S. Law (3) , Mai Pham (3) , E. Le Flochmoën (1) , C. Liousse (1) , V. H. Peuch (5) , G. D. Carver (4) , J. A. Pyle (4) , B. Sauvage (1) , P. van Velthoven (2) , H. Schlager (6) , C. Mari (1) , Jean-Pierre Cammas (1)

1 LAERO - Laboratoire d'aérologie
2 KNMI - Royal Netherlands Meteorological Institute
3 TROPO - LATMOS
4 Centre for Atmospheric Science [Cambridge, UK]
5 CNRM - Centre national de recherches météorologiques
6 IPA - DLR Institut für Physik der Atmosphäre = DLR Institute of Atmospheric Physics

Within the African Monsoon Multidisciplinary Analysis (AMMA), we investigate the impact of nitrogen oxides produced by lightning (LiNO_x) and convective transport during the West African Monsoon (WAM) upon the composition of the upper troposphere (UT) in the tropics. For this purpose, we have performed simulations with 4 state-of-the-art chemistry transport models involved within AMMA, namely MOCAGE, TM4, LMDz-INCA and p-TOMCAT. The model intercomparison is complemented with an evaluation of the simulations based on both spaceborne and airborne observations. The baseline simulations show important differences between the UT CO and O₃ distributions simulated by each of the 4 models when compared to measurements from the MOZAIC program and fom the Aura/MLS spaceborne sensor. We show that such model discrepancies can be explained by differences in the convective transport parameterizations and, more particularly, the altitude reached by convective updrafts (ranging between ~200-125 hPa). Concerning UT O₃, the models exhibit a good agreement with the main observed features. Nevertheless the majority of models simulate low O₃ concentrations compared to both MOZAIC and Aura/MLS observations south of the equator, and rather high concentrations in the Northern Hemisphere. Sensitivity studies are performed to quantify the effect of deep convective transport and the influence of LiNO_x production on the UT composition. These clearly indicate that the CO maxima and the elevated O₃ concentrations south of the equator are due to convective uplift of air masses impacted by Southern African biomass burning, in agreement with previous studies. Moreover, during the WAM, LiNO_x from Africa are responsible for the highest UT O₃ enhancements (10-20 ppbv) over the tropical Atlantic between 10° S-20° N. Differences between models are primarily due to the performance of the parameterizations used to simulate lightning activity which are evaluated using spaceborne observations of flash frequency. Combined with comparisons of in-situ NO measurements we show that the models producing the highest amounts of LiNO_x over Africa during the WAM (INCA and p-TOMCAT) capture observed NO profiles with the best accuracy, although they both overestimate lightning activity over the Sahel.

Domaines: Physique Atmosphérique et Océanique [physics.ao-ph]

Brice Barret, J. E. Williams, Idir Bouarar, X. Yang, B. Josse, et al.. Impact of West African Monsoon convective transport and lightning NO_x production upon the upper tropospheric composition: a multi-model study. Atmospheric Chemistry and Physics, 2010, 10 (12), pp.5719-5738. ⟨10.5194/acp-10-5719-2010⟩. ⟨hal-00457507⟩