(Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water. - Archive ouverte HAL Access content directly
Journal Articles Dalton Transactions Year : 2010

(Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water.

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Abstract

Covalent embedding of a (eta(6)-arene) ruthenium(II) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels-Alder reaction enhanced by two orders of magnitude in water.
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Dates and versions

hal-00738766 , version 1 (24-05-2013)

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Barisa Talbi, Pierre Haquette, Annie Martel, Frédéric de Montigny, Céline Fosse, et al.. (Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water.. Dalton Transactions, 2010, 39 (24), pp.5605-7. ⟨10.1039/c001630f⟩. ⟨hal-00738766⟩
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