Tropospheric nitric acid columns from the IASI satellite instrument interpreted with a chemical transport model: Implications for parameterizations of nitric oxide production by lightning

Matthew Cooper (1) , Randall V. Martin (1, 2) , Catherine Wespes (3) , Pierre-François Coheur (3) , Cathy Clerbaux (4) , Lee T. Murray (5)

1 Department of Physics and Atmospheric Science [Halifax]
2 CfA - Harvard-Smithsonian Center for Astrophysics
3 Spectroscopie de l'atmosphère, Service de Chimie Quantique et Photophysique
4 TROPO - LATMOS
5 GISS - NASA Goddard Institute for Space Studies

This paper interprets tropical tropospheric nitric acid columns from the IASI satellite instrument with a global chemical transport model (GEOS-Chem). GEOS-Chem columns generally agree with IASI over the tropical ocean to within 10%. However the GEOS-Chem simulation underestimates IASI nitric acid over Southeast Asia by a factor of two. The regional nitric acid bias is confirmed by comparing the GEOS-Chem simulation with additional satellite (HIRDLS, ACE-FTS) and aircraft (PEM-Tropics A and PEM-West B) observations of the middle and upper troposphere. This bias is likely driven by the lightning NOx parameterization, both in terms of the magnitude of the NOx source and the ozone production efficiency of concentrated lightning NOx plumes. We tested a subgrid lightning plume parameterization and found that an ozone production efficiency of 15 mol/mol in lightning plumes over Southeast Asia in conjunction with an additional 0.5 Tg N would reduce the regional nitric acid bias from 92% to 6% without perturbing the rest of the tropics. Other sensitivity studies such as modified NOx yield per flash, increased altitude of lightning NOx emissions, decreased convective mass flux, or increased scavenging of nitric acid required unrealistic changes to reduce the bias.

Mots clés: Nitric Acid; Tropospheric Chemistry; Lightning NOx

Domaines: Physique Atmosphérique et Océanique [physics.ao-ph]; Sciences de l'environnement

Matthew Cooper, Randall V. Martin, Catherine Wespes, Pierre-François Coheur, Cathy Clerbaux, et al.. Tropospheric nitric acid columns from the IASI satellite instrument interpreted with a chemical transport model: Implications for parameterizations of nitric oxide production by lightning. Journal of Geophysical Research: Atmospheres, 2014, 119 (16), pp.10068-10079. ⟨10.1002/2014JD021907⟩. ⟨hal-01056707⟩