1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion - Université Pierre et Marie Curie Accéder directement au contenu
Article Dans Une Revue Journal of the American Chemical Society Année : 2014

1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion

Résumé

An intramolecular 1,2(α)-H migration in a saturated ruthenium stannylene complex, to form a ruthenostannylene complex, involves a reversal of the role for a coordinated stannylene ligand, from that of an electron donor to an acceptor in the transition state. This change in the bonding properties for a stannylene group, with a simple molecular motion, lifts the usual requirement for generation of an unsaturated metal center in migration chemistry.
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Dates et versions

hal-01072716 , version 1 (08-10-2014)

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Hsueh-Ju Liu, Julie Guihaumé, Thomas Davin, Christophe Raynaud, Odile Eisenstein, et al.. 1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion. Journal of the American Chemical Society, 2014, 136, pp.13991-13994. ⟨10.1021/ja507799e⟩. ⟨hal-01072716⟩
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