Detection and Identification of the Keto-Hydroperoxide (HOOCH 2 OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether

Kai Moshammer (1) , Ahren Jasper , Denisia Popolan-Vaida , Arnas Lucassen , Pascal Diévart , Hatem Selim , Arkke Eskola , Craig Taatjes , Stephen Leone , S. Mani Sarathy (2) , Yiguang Ju (3) , Philippe Dagaut (4) , Katharina Kohse-Höinghaus (5) , Nils Hansen

1 PTB - Physikalisch-Technische Bundesanstalt [Braunschweig]
2 Clean Combustion Research Center - CCRC (Thuwal, Saudi Arabia)
3 MAE - Department of Mechanical and Aerospace Engineering [Princeton]
4 ICARE - Institut de Combustion, Aérothermique, Réactivité et Environnement
5 Universität Bielefeld

Mots clés: synchrotron; Jet-stirred reactor; Ketohydroperoxide; Dimethyl ether

Domaines: Chimie théorique et/ou physique; Milieux fluides et réactifs

Kai Moshammer, Ahren Jasper, Denisia Popolan-Vaida, Arnas Lucassen, Pascal Diévart, et al.. Detection and Identification of the Keto-Hydroperoxide (HOOCH 2 OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether. Journal of Physical Chemistry A, 2015, 119 (28), pp.7361-7374. ⟨10.1021/acs.jpca.5b00101⟩. ⟨hal-02014646⟩