Thermodynamic properties of THF + CO2 hydrates in relation with refrigeration applications

María del Carmen Martínez 1 Didier Dalmazzone 2 Walter Fürst 2 Anthony Delahaye 1 Laurence Fournaison 1
1 UR GPAN - Génie des procédés frigorifiques
2 GDP - Génie des Procédés
Abstract : Clathrate hydrate slurries are promising systems in the field of cold distribution. In this work, the Lw-H-V equilibrium conditions, the dissociation enthalpy, and the CO2 hydration number of a clathrate hydrate formed from THF/CO2/water mixtures were studied, using a DSC method. For equilibrium condition determination, THF concentration was varied from 1.0 to 16.0 wt % and CO2 partial pressure range was 0.2 to 2.0 MPa. For enthalpy measurements, THF concentration was fixed at 19 wt % and CO2 partial pressure investigated from 0.2 to 2.0 MPa. Experimental equilibrium temperatures and enthalpy values were in good agreement with the results of a model combining the van der Waals and Platteeuw approach with the RKS equation of state associated to a MHV2 mixing rule and UNIFAC model. Equilibrium conditions and dissociation enthalpy show that THF + CO2 hydrate slurries are promising mixtures for refrigeration application. © 2008 American Institute of Chemical Engineers.
Mots-clés : Règle mélange Equation état Modélisation Pression partielle Calorimétrie différentielle balayage Hydratation Enthalpie Clathrate Réfrigération Dioxyde de carbone Propriété thermodynamique
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Journal articles
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https://hal-ensta-paris.archives-ouvertes.fr//hal-00848775
Contributor : Aurélien Arnoux <>
Submitted on : Tuesday, July 30, 2013 - 4:43:15 PM
Last modification on : Wednesday, February 19, 2020 - 9:22:23 AM

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María del Carmen Martínez, Didier Dalmazzone, Walter Fürst, Anthony Delahaye, Laurence Fournaison. Thermodynamic properties of THF + CO2 hydrates in relation with refrigeration applications. AIChE Journal, Wiley, 2008, 54 (4), pp.1088-1095. ⟨10.1002/aic.11455⟩. ⟨hal-00848775⟩

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